I’ve started a little series on how to migrate your MySQL applications and databases over to CouchDB. Most of the process is about how you think about your data, not about the database itself, the application, or the interface to the database storage. There are some use cases for data storage that lend themselves to the CouchDB document model that provides some advantages over the table-based structure in MySQL.
The first part of the series is Moving from MySQL to CouchDB: Part 1.